3D Mapping of Carbon Nanotube Distribution in Composite Materials
Come: Chinese Academy of Sciences Date: 2015-07-07 17:20:15
Researchers from the Massachusetts Institute of Technology and the University of Maryland also contributed to the study. The overall properties of carbon nanotubes largely depend on the manner in which they are arranged and distributed in a material. The data will enable researchers who study composite materials to design and test realistic computer models of materials with varied electrical, thermal and mechanical features.
Carbon fiber composites are known for their light weight and high strength. Carbon nanotube (CNT) composites or nanocomposites with smaller and more number of carbon filaments not only exhibit high strength, but are also good conductors of heat and electricity.
Alex Liddle from NIST, an author of this research paper stated that while researchers were able to determine the bulk properties of a nanocomposite, they did not know precisely why different composite formulations exhibited different properties.
Figuring out why these materials have the properties they do requires a detailed, quantitative understanding of their complex 3-D structure. We need to know not only the concentration of nanotubes but also their shape and position, and relate that to the properties of the material.
Liddle
It is a challenge to view the arrangement of carbon nanotubes in composites as they are enclosed by an epoxy resin, which also contains carbon atoms. Even with advanced probes, the contrast is very low for software image processors to differentiate them easily.
It is truly tedious to mark thousands of carbon nanotubes in an image. Therefore, Bharath Natarajan from NIST developed an image processing algorithm that can differentiate CNTs from an epoxy resin.
The full potential of a CNT in terms of its strength and its electrical and thermal conductivity is realized when it is straight and stretched out however when CNTs are suspended in an epoxy resin, they spread out, bundle and twist into different shapes. Our analysis revealed that the benefits of CNTs increases in a non-linear fashion as their concentration increases. As the concentration raises, the CNTs come into contact, increasing the number of intersections, which increases their electrical and thermal conductivity, and the physical contact causes them to conform to one another, which straightens them, increasing the materials strength.
The fact that improving the CNT concentration enhances its properties is not strange but now researchers realize how this influences the properties of materials and why previous models of the performance of nanocomposite materials never matched their actual performance.
We have really only seen the tip of the iceberg with respect to this class of material. There are all sort of ways other researchers might slice and dice the data to model and eventually manufacture optimal materials for thermal management, mechanical reinforcement, energy storage, drug transport and other uses.
A part of this research was conducted at NISTs Center for Nanoscale Science and Technology (CNST), a national user facility available to researchers from industry, academia and government.
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